Resistivity of metals like iron and copper is 0.1 x 10-6 Ω·m and 1.7 x 10-8 Ω·m . The resistivity of insulators like glass is 9 x 10-11 Ω·m , whereas the resistivity of semiconductor substance are between 10-4 to 0.5 Ω·m . Thus those substance which have resistivity lower than insulators and higher than conductors are the semiconductors.
Pure silicon crystal (source : www.images-of-elements.com) |
- The resistivity of the semiconductor decreases with temperature an vice versa (semiconductor materials behaves as insulator at absolute zero (zero Fahrenheit))
- The second and the most important property is that if suitable impurity are added (doped) to a semiconductor block like arsenic,gallium , phosphorous the current conducting property increases , giving rise to a new improved semiconductor block with high conductivity "Extrinsic semiconductor "
Extrinsic semiconductor are mainly of two kinds "the P-type" and the "the N-type" . The P-type semiconductor are created by doping impurities with valency 3 (trivalent) like boron,aluminium etc and N- type semiconductors are created by doping impurities with valency 5 (pentavalent) impurity like arsenic and phosphorous .
like in a silicon crystal with valency 4 when a trivalent impurity (impurity for p-type semiconductor) is doped the 3 outer electron (valence electron) of silicon crystal form a covalent bond with the 3 electron of the trivalent impurity . But in the fourth covalent bond only silicon atom contributes one valence electron and there is a deficiency of electron which is called a hole .Holes are positively charged and are the prime charge carrier in P-type semiconductor.
Whereas when a pentavalent(valency 5) impurity are doped the four atoms of silicon forms a covalent bond with the 4 valence electron of impurity leaving behind one free electron . These free Electrons are the prime charge carrier of N-type semiconductor.
N-type semiconductor is more preferred then P-type as the mobility (drift velocity to applied electric field across material) of electrons ( prime charge carrier of N-type) is greater than that of holes (charge carrier of P-type).